Unfilled PEEK: Properties and Applications in Defense Assemblies
Unfilled PEEK (neat PEEK, natural grade) is the baseline against which all filled grades are measured. It provides continuous service temperature of 260°C (500°F), tensile strength of 14,000 PSI, compressive strength of 18,000 PSI, flexural modulus of 600,000 PSI, and chemical resistance to virtually all organic solvents, hydraulic fluids, fuels, and steam. Its dielectric strength is approximately 480 V/mil, making it an excellent electrical insulator — a property that disappears when conductive fillers are added.
In Oshkosh defense programs, unfilled PEEK appears in bearing cages, seal retainers, bushings in hydraulic systems, standoffs and spacers in high-voltage electronic assemblies, and wear pads in vehicle mechanical linkages. The material's FDA compliance (unfilled PEEK meets FDA 21 CFR requirements) is irrelevant to defense, but its USP Class VI biocompatibility is sometimes leveraged in medical device work that overlaps with the Fox Valley precision machining community.
Machining unfilled PEEK requires carbide tooling with sharp cutting edges, positive rake angles, and consistent coolant application to prevent thermal buildup. The material's glass transition temperature is 143°C — well above what normal machining generates, but localized heat from dull tooling or interrupted chip evacuation can soften the polymer and cause dimensional instability. Recommended surface speeds: 800–1,200 SFM for turning, 500–800 SFM for milling, with through-spindle or flood coolant to maintain chip temperature below 100°C. Tolerances of ±0.001 inch are routinely achievable on well-maintained CNC equipment with proper workholding.
Glass-Filled PEEK: Stiffness for Structural Load-Bearing Components
Glass-filled PEEK (typically 30% short glass fiber by weight, designated GF30 or 30% GF) trades some of unfilled PEEK's chemical resistance and electrical insulation for significantly higher stiffness and reduced creep. Tensile strength increases to approximately 21,000 PSI, flexural modulus approximately doubles to 1,200,000 PSI, and the coefficient of thermal expansion (CTE) drops closer to aluminum — reducing differential thermal expansion issues when PEEK components mount against metal structures.
For Oshkosh-area heavy-equipment programs, glass-filled PEEK is the correct grade for structural brackets, motor housings in power-dense drive systems, fluid manifold bodies in chemical environments, and bearing housings where long-term creep under sustained load would cause unfilled PEEK to drift out of tolerance. The glass fibers are abrasive — tool wear rates with GF30 PEEK run 3–5 times higher than with unfilled PEEK. Carbide tooling with PCD (polycrystalline diamond) edge preparation is recommended for production runs above 50 pieces; otherwise plan for insert changes every 20–30 parts on tight-tolerance features.
GF30 PEEK is not appropriate when electrical insulation is required — the glass fiber content slightly reduces dielectric strength, and more importantly, glass-fiber composite surfaces are microscopically porous in a way that can trap moisture and degrade insulation resistance over time. For electronics enclosures requiring both stiffness and insulation, unfilled PEEK remains the correct choice.
Carbon-Filled PEEK: Bearing, Wear, and Tribological Applications
Carbon-filled PEEK (CF30 or CF15 — 15–30% carbon fiber or carbon particles) is the grade specified when wear resistance, low friction, and maximum stiffness are the primary requirements. The carbon filler serves as a solid lubricant — reducing the coefficient of friction from unfilled PEEK's 0.35–0.45 against steel to 0.10–0.20 for carbon-filled grades. Flexural modulus for CF30 reaches 2,000,000+ PSI, approaching the lower range of aluminum. Compressive strength exceeds 25,000 PSI.
In Oshkosh defense and equipment programs, carbon-filled PEEK appears in dry-running bearing rings, bushings in articulating joints, piston rings and seal rings in hydraulic equipment where oil-free operation is required, and wear strips in guide systems. Its electrical conductivity (carbon filler makes the material semi-conductive to slightly conductive) is a design consideration — CF PEEK will not build static charge, which is useful in electronics assembly environments but rules it out for electrical isolation applications.
Machining CF30 PEEK requires the same carbide tooling discipline as GF30 but with additional attention to edge sharpness — carbon fiber composites produce fraying and delamination at machined edges when tools are dull, and that fraying shows up as dimensional non-conformance on bore diameters and chamfers. PCD tooling extends life significantly on production runs. Surface finish achievable: 32 Ra or better with sharp carbide, 16 Ra or better with PCD. One handling note: carbon fiber PEEK dust is electrically conductive — shop ventilation and cleanup procedures should prevent chip and dust accumulation on electrical panels.
Grade Selection and Regional Sourcing for PEEK in the Fox Valley
Selecting the right PEEK grade for an Oshkosh defense or equipment program follows a logical decision tree: start with unfilled PEEK if electrical insulation, food/drug compliance, or maximum chemical resistance is required; upgrade to GF30 if creep under sustained load or stiffness matching aluminum is the driver; specify CF30 if dry-running wear or friction reduction is the primary need. Combinations (glass-and-carbon-filled PEEK, PTFE-filled PEEK for ultra-low friction) are available from specialty compounders but carry 6–10 week lead times.
Material availability in the Fox Valley: PEEK rod and plate in standard diameters (0.25–4 inch rod, 0.25–2 inch plate) is stocked by industrial plastics distributors in Milwaukee, Appleton, and Green Bay — delivery to Oshkosh typically 1–3 business days for stock grades. Large cross-sections (rod above 4 inch diameter, thick plate) are less commonly stocked and may require 3–6 weeks from specialty polymer distributors. Victrex, Solvay (KetaSpire), and RTP Company are the primary material producers; shops should confirm the material brand on the cert, as commodity PEEK from offshore sources has been found to contain recycled or substandard resin that does not meet published mechanical property specifications.