Unfilled vs. Glass-Filled vs. Carbon-Filled PEEK: When Each Grade Applies
Unfilled PEEK in natural (tan/beige) color is the baseline specification when chemical purity, FDA compliance for food-contact or implant-adjacent applications, or MRI compatibility are requirements. Tensile strength runs 14,500 psi, flexural modulus approximately 600,000 psi, and elongation 30 to 50 percent โ relatively flexible for an engineering plastic. Unfilled PEEK machines with less tool wear than filled grades, holds tight tolerances well because thermal expansion is moderate (2.6 x 10 to the -5 per degree Fahrenheit), and produces a cleanable surface that does not harbor contaminants in medical and semiconductor applications. The primary limitation is wear: in sliding contact applications, unfilled PEEK wears relatively quickly.
Glass-filled PEEK (typically 30 percent short glass fiber by weight) increases flexural modulus to approximately 1,400,000 psi โ more than double unfilled โ and improves creep resistance under sustained load at elevated temperature. The glass filler reduces elongation to about 2 percent, making the material stiffer and more brittle in thin sections. Glass-filled PEEK is the default for structural brackets, bearing cages, and stiffened housings where dimensional stability under load and temperature is the primary requirement. The trade-off is accelerated tool wear: glass fiber is abrasive to cutting edges, and polycrystalline diamond (PCD) tooling or frequent carbide insert changes are required to maintain surface quality on production quantities.
Carbon-filled PEEK (30 percent short carbon fiber) brings flexural modulus above 2,100,000 psi, adds electrical conductivity (resistivity drops to roughly 10 to the 2 ohm-cm, compared with 10 to the 15 for unfilled), and significantly improves dry-running tribological performance. Carbon fiber in the matrix acts as a solid lubricant in sliding applications, reducing the coefficient of friction from 0.35 (unfilled on steel) to approximately 0.15. For bearing surfaces, thrust washers, and seal rings in offshore pumps or aerospace actuators, carbon-filled PEEK extends service intervals substantially versus unfilled or glass-filled grades. The black color and electrical conductivity also address ESD concerns in semiconductor and defense electronics environments.