Unfilled PEEK: The Starting Point for Medical and Fluid-System Applications
Unfilled PEEK (natural, ivory-colored) is the baseline grade specified when biocompatibility, chemical resistance, or sterilizability is the primary driver. Its tensile strength of 14,000 psi, flexural modulus of 580,000 psi, and continuous-use temperature of 250°C (480°F) enable it to survive steam autoclave cycles at 134°C with no degradation — a property that makes it irreplaceable for reusable surgical instrumentation, endoscope components, and implantable device hardware. ISO 10993 biocompatibility testing has been completed on major PEEK grades (Victrex PEEK 150G, Solvay KetaSpire), and FDA drug master file submissions exist for implant-grade variants, which streamlines regulatory pathways for Evansville medical device suppliers.
Machining unfilled PEEK requires attention to several non-obvious process variables. The material is abrasive — cutting edges dull faster than on aluminum — and its low thermal conductivity (0.25 W/m·K, versus aluminum's 167 W/m·K) means heat accumulates at the cutting zone rather than dissipating into the workpiece. Sharp, uncoated carbide tooling with high positive rake (10–15°) and cutting speeds of 600–900 SFM with light feeds (0.004–0.008 IPR) produce clean surfaces and preserve edge life. Compressed air cooling is preferred over flood coolant in medical applications to avoid contamination; for aerospace and industrial parts, standard soluble coolant is acceptable. Internal stress in extruded PEEK rod can cause distortion when material is removed — annealing at 200°C for 4 hours before final machining is standard practice in precision medical component shops.
Glass-Filled PEEK for Structural and Wear-Resistance Upgrades
Glass-filled PEEK (30% glass fiber by weight is the most common loading, though 10% and 20% variants exist) increases tensile strength to 24,000 psi, flexural modulus to 1,600,000 psi, and reduces the coefficient of thermal expansion (CTE) from 47 ppm/°C (unfilled) to approximately 20 ppm/°C. That CTE reduction is the critical design reason to specify 30GF PEEK in assemblies where PEEK components are bolted to metal housings — a bolted PEEK-to-aluminum joint in a 150°C underhood environment with unfilled PEEK will develop joint loosening from differential thermal expansion; 30GF PEEK stays tight.
The trade-off for glass filling is significantly higher tool wear — the glass fibers are abrasive and accelerate flank wear on carbide cutting edges by 3–5× compared to unfilled PEEK. Shops machining 30GF PEEK in production should budget for more frequent insert changes or invest in diamond-coated tooling (CVD diamond or PCD) that handles the abrasion. Cutting speeds should drop to 400–600 SFM versus the 600–900 SFM used on unfilled PEEK. Surface finish achievable on 30GF PEEK is Ra 32–63 µin on turned diameters — the glass fibers prevent the Ra 8–16 µin achievable on unfilled PEEK without a polishing step. For Evansville automotive buyers using 30GF PEEK in sensor housings, electrical connectors, and bearing cages, these machining parameters are well within the capability of the regional CNC shops supporting Toyota's supplier network.
Carbon-Filled PEEK for Bearing, Seal, and High-Load Applications
Carbon-filled PEEK (typically 30% carbon fiber, CF30) increases stiffness further (flexural modulus to 2,200,000 psi) and, more importantly, dramatically improves tribological performance. The PV limit (pressure × velocity) of CF30 PEEK in dry sliding contact is 15,000–20,000 psi·fpm, compared to 4,000–6,000 for unfilled PEEK — this is why CF30 PEEK is the standard material for thrust washers, back-up rings, valve seats, and compressor piston rings in applications where lubricated bearings are impractical.
The electrical conductivity of carbon fibers gives CF30 PEEK a surface resistivity in the 10²–10⁴ Ω/sq range, which is both useful (ESD protection in electronic assembly fixtures) and potentially problematic (continuity in implantable devices). In Evansville's pharmaceutical packaging machinery — where precision linear bearings and seal rings operate in clean-in-place (CIP) environments with caustic cleaning solutions at 80°C — CF30 PEEK is increasingly replacing UHMWPE and PTFE-filled components because it holds tighter dimensional tolerances under load and doesn't creep under continuous bearing stress. Machining CF30 PEEK follows similar parameters to 30GF PEEK, with the caveat that carbon fiber dust is a respiratory and electrical hazard — proper dust extraction at the machine and grounded fixturing are required.