Unfilled PEEK in Fluid Handling and Bearing Applications
Unfilled PEEK — semicrystalline polymer, density 1.32 g/cm³, continuous service temperature 250°C — is the baseline specification for components where chemical resistance and thermal performance are primary drivers and dimensional precision is critical. In slurry pump applications common to Iron Range taconite processing, PEEK wear rings and throat bushings outperform bronze in acidic iron slurry environments (pH 3.5-6.5, iron sulfate concentration) where bronze corrodes rapidly and releases metal ions that contaminate process water. PEEK's chemical resistance spans sulfuric acid up to 30 percent concentration, hydrochloric acid, and hydrofluoric acid at limited concentrations — the chemical exposure profile of mineral processing operations.
Machined unfilled PEEK holds tolerances of ±0.025 mm on bores and diameters with proper tooling and temperature-controlled inspection. Its low coefficient of friction against steel (0.35-0.45 µk dry) and good PV rating (0.06 MPa·m/s continuous) make it a practical bearing material in lightly lubricated or dry-running applications. For Duluth marine applications — stern tube bearing wear rings, water-lubricated strut bearings, sea water pump impeller sleeves — PEEK's water absorption of only 0.5 percent (versus 1.5-3 percent for nylon) maintains dimensional stability in constant water immersion, which is a real engineering advantage when diametral clearances of 0.05-0.10 mm determine pump efficiency.
PEEK billet for machining is available in natural (tan/beige), which indicates unfilled virgin resin, and in black, which typically indicates a compounded grade — buyers should confirm grade and filler content from the supplier's material certification before specifying 'unfilled PEEK' and accepting a black-pigmented part. Color alone does not guarantee grade; request Victrex, Solvay Ketaspire, or equivalent manufacturer's certificate of conformance with each order.
Glass-Filled PEEK for Structural Load-Bearing Components
30 percent glass-filled PEEK raises flexural modulus from 3.6 GPa (unfilled) to approximately 10 GPa — close to aluminum — while increasing compressive strength from 120 MPa to 160 MPa. The stiffness increase makes glass-filled PEEK (GF-30 PEEK) the grade of choice for structural brackets, bushings under high radial load, and housings where dimensional stability under sustained load matters more than friction properties. For Duluth mining equipment conveyor components — guide blocks, chain slider bars, support pads — GF-30 PEEK's combination of stiffness, temperature resistance, and chemical inertness eliminates the periodic replacement cycle that acetal and nylon components require in abrasive slurry environments.
The trade-off with glass fill is tribological performance: the glass fibers, while increasing strength, abrade mating metal surfaces when used as a bearing material against soft substrates. GF-30 PEEK should not be specified as a bearing material against polished aluminum shafts — it will score the aluminum. Against hardened steel (58 HRC minimum) or stainless steel, glass-filled PEEK performs acceptably in moderate PV applications. For pure bearing applications, unfilled PEEK or carbon-filled PEEK is the better grade.
Machining GF-30 PEEK requires carbide tooling — glass fiber rapidly dulls HSS — and positive rake angles to minimize heat generation. The glass fiber's abrasiveness means tool changes are more frequent than for unfilled PEEK, and shops must account for this in quoting precision components. Duluth shops with experience in glass-filled composites and ceramic materials adapt most readily to GF-30 PEEK machining protocols.
Carbon-Filled PEEK for Self-Lubricating Bearing and Seal Components
30 percent carbon-fiber-filled PEEK combines the base polymer's thermal and chemical resistance with dramatically improved tribological properties. Carbon fiber fill reduces the dry coefficient of friction against steel to 0.15-0.20, compared to 0.35-0.45 for unfilled PEEK, and raises the continuous PV rating to 0.12-0.18 MPa·m/s — two to three times unfilled PEEK. For Duluth applications in mining equipment and marine machinery where lubrication access is difficult or where lubricant contamination of process fluids is prohibited, CF-30 PEEK delivers the bearing performance of a lubricated bronze bushing without any lubricant.
Electrical conductivity is a secondary benefit of carbon fill — CF-30 PEEK's resistivity drops to 10^2-10^4 Ω·cm from unfilled PEEK's 10^16 Ω·cm, which dissipates static charge buildup in powder handling and fuel transfer applications. For Iron Range iron ore pellet handling conveyor systems where electrostatic charge on dry pellets creates discharge hazards, CF-30 PEEK slider bars and guide components address both the wear and the static issues simultaneously.
Dimensional stability of CF-30 PEEK exceeds both unfilled and glass-filled grades because carbon fiber reduces the coefficient of thermal expansion to approximately 14 µm/m·°C (versus 50 µm/m·°C for unfilled PEEK). This lower CTE makes CF-30 PEEK the preferred grade for precision bearing fits and seal components where thermal cycling — from Duluth's -30°C winter to operational temperatures of 150-200°C — would otherwise open critical clearances. When designing press-fit or transition-fit PEEK components for steel housings, the CTE mismatch between PEEK and steel must be calculated across the full service temperature range to ensure the fit remains functional at temperature extremes.