PEEK Grades and Their Oilfield Relevance: Unfilled, Glass-Filled, and Carbon-Filled
Unfilled PEEK (natural tan or off-white) is the baseline grade offering the highest chemical resistance and best electrical insulation properties. With a dielectric strength above 480 volts per mil and resistance to virtually all oilfield chemicals including H2S, CO2, methanol, hydrochloric acid at typical stimulation concentrations, and most glycol-based fluids, unfilled PEEK is the grade for electrical isolation components, corrosion-resistant seal backup rings, and chemical injection check valve components in downhole and surface applications. Its compressive strength around 25,000 psi and flexural modulus around 600,000 psi provide meaningful structural capability even without fillers.
Glass-filled PEEK (typically 30% glass fiber by weight) trades some chemical resistance and electrical insulation for a 50 to 60% improvement in flexural modulus, reduced thermal expansion coefficient, and better dimensional stability under cyclic load. For structural wear components — guide rings in reciprocating pump assemblies, centralizer rings on downhole tools, and bearing pads in ESP (electric submersible pump) systems — glass-filled PEEK maintains tighter clearances over the operating temperature range because it expands and contracts less than unfilled material. The glass content makes it abrasive on cutting tools and requires different speeds and feeds than unfilled grades.
Carbon-filled PEEK (30% carbon fiber) delivers the highest stiffness and lowest thermal expansion of the three grades, along with electrical conductivity that can prevent static charge buildup in certain pneumatic conveying or fuel system components. Its compressive strength approaches 35,000 psi. For downhole centralizers, wear rings in high-load ESP stages, and precision bearing cages, carbon-filled PEEK is the specification when dimensional stability over a wide temperature range is the primary constraint. The carbon content also provides inherent lubricity, reducing the coefficient of friction in sliding contact applications. However, carbon-filled PEEK is harder to machine than unfilled and typically commands the highest per-piece cost of the three grades.
Machining PEEK to Tight Tolerances in a CNC Environment
PEEK machines more like aluminum than like most plastics — it responds well to sharp carbide tooling, handles high speeds and positive rake angles, and does not melt or smear at the cutting interface the way softer polymers do. Unfilled PEEK can be cut at surface speeds of 400 to 600 surface feet per minute with light feeds, achieving surface finishes of 32 Ra microinch without a dedicated finishing pass. This is important for sealing surfaces on O-ring grooves and backup ring interfaces, where 32 Ra or better is a common callout.
Dimensional tolerances for PEEK components depend on section size and temperature during machining. Thin-walled rings and bushings made from PEEK can stress-relieve and shift dimensions if turned directly from cold-stored stock without temperature conditioning. Best practice for tight-tolerance PEEK parts is to machine the component near its nominal final temperature, allow time for stress relaxation after roughing, then take finish passes to final dimensions. For parts held to plus or minus 0.001 inch or better, this sequence is not optional — it is the difference between first-article pass and scrap. Casper shops with polymer machining experience understand this; shops that primarily cut metal may not.
Post-machining annealing of PEEK — heating to approximately 300 degrees Fahrenheit for one hour per inch of section thickness, then slow cooling — releases residual stresses and stabilizes dimensions for parts that will see elevated temperatures in service. For downhole components that will cycle from ambient to 250 degrees Fahrenheit repeatedly, post-machine anneal is a recommended step that should be specified on the drawing rather than assumed.