Grade Differences: Delrin 150, Acetal Copolymer, and Acetal Homopolymer
Delrin 150 is DuPont's flagship acetal homopolymer grade, the original commercial polyoxymethylene (POM) resin and still the reference standard for precision machined acetal components. Its high molecular weight (150 in the grade designation refers to the melt flow index range) and highly crystalline structure produce tensile strength of 10,000 psi, flexural modulus of 450,000 psi, and a Rockwell hardness of M90 — numbers that hold up well against engineering metals on a strength-to-weight basis. Delrin 150 machines to exceptional surface finish and tight tolerances, making it the default grade for precision gears, cams, bushings, and slide components where dimensional accuracy is the primary specification driver.
Acetal homopolymer's crystalline structure comes with one recognized limitation: centerline porosity in rod and slab stock larger than approximately 2 inch diameter. As the melt cools inward from the surface during extrusion, crystallization shrinkage creates voids at the centerline of large-diameter rod. For components machined from small-diameter rod (under 2 inches), this is rarely a concern. For large bushings, gears, or blocks machined from plate or large-diameter rod, centerline porosity can appear as voids in machined faces — a quality issue that surprises shops not familiar with the material's behavior.
Acetal copolymer (also sold as POM-C or under trade names like Celcon, Hostaform, and Kepital) addresses the centerline porosity issue through a modified polymerization process that incorporates a small percentage of ethylene oxide comonomers, disrupting the pure crystalline structure enough to eliminate void formation in large cross-sections. Copolymer tensile strength (8,800 psi) and modulus (380,000 psi) are slightly lower than Delrin 150, and surface finish after machining is marginally less lustrous, but for large cross-section components the elimination of porosity risk more than compensates. Copolymer also has slightly better chemical resistance in alkaline environments — important for components exposed to cleaning chemicals in RV and commercial kitchen applications.
The practical sourcing distinction: Delrin 150 (homopolymer) dominates precision small-part production; copolymer is specified when large cross-section stock is required or when alkaline chemical resistance is the design driver.